Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi: 10.1039/C5CC08486E) (PMID:26581307)
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Abstract
We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2]23− (M = CoII or MnII), which contain {PW6} fragments generated from the [P2W15O56]12− precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cameron, Mr Jamie and Martin, Miss Merce and Winter, Mr Ross and Cronin, Professor Lee |
| Authors: | Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548 |
| Published Online: | 09 November 2015 |
| Copyright Holders: | Copyright © 2016 Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 52(5):919-921 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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