Wiles, A. A. , Zhang, X., Fitzpatrick, B., Long, D.-L. , Macgregor, S. A. and Cooke, G. (2016) Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries. Dalton Transactions, 45(17), pp. 7220-7225. (doi: 10.1039/C6DT00875E) (PMID:27063914)
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Abstract
Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state. We have further investigated the ability of these reactions to facilitate redox-auxiliary-like reactivity by further hydrogenolyisis of the Diels–Alder adduct to the corresponding cyclopentane derivative.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Cooke, Professor Graeme and Wiles, Dr Alan and Fitzpatrick, Dr Brian and Long, Dr Deliang |
Authors: | Wiles, A. A., Zhang, X., Fitzpatrick, B., Long, D.-L., Macgregor, S. A., and Cooke, G. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
Publisher: | Royal Society of Chemistry |
ISSN: | 1477-9226 |
Published Online: | 11 April 2016 |
Copyright Holders: | Copyright © 2016 Royal Society of Chemistry |
First Published: | First published in Dalton Transactions 45(17):7220-7225 |
Publisher Policy: | Reproduced under a Creative Commons License |
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