Anamimoghadam, O., Long, D. L. and Bucher, G. (2014) 9-Iodophenalenone and 9-trifluoromethanesulfonyloxyphenalenone: convenient entry points to new phenalenones functionalised at the 9-position: iodine-carbonyl interaction studies by X-ray crystallography. RSC Advances, 4(100), pp. 56654-56657. (doi: 10.1039/c4ra00178h)
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Abstract
Reaction of 9-hydroxyphenalenone 1 with triflic anhydride allows access to 9-trifluoromethanesulfonyloxyphenalenone 2. The reactivity of 2 is explored in the reactions with pyridine, iodide, and azide. Structural aspects of 4, including carbonyl–iodine interactions, are investigated by X-ray crystallography. Both 2 and 9-iodophenalenone 4 are expected to be valuable precursors in the synthesis of further 9-functionalised phenalenones.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Bucher, Dr Goetz and Anamimoghadam, Mr Ommid and Long, Dr Deliang |
| Authors: | Anamimoghadam, O., Long, D. L., and Bucher, G. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | RSC Advances |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 2046-2069 |
| ISSN (Online): | 2046-2069 |
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