Craig, G. A., Marbey, J. J., Hill, S., Roubeau, O., Parsons, S. and Murrie, M. (2015) Field-induced slow relaxation in a monometallic manganese(III) single-molecule magnet. Inorganic Chemistry, 54(1), pp. 13-15. (doi: 10.1021/ic5024136)
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Publisher's URL: http://dx.doi.org/10.1021/ic5024136
Abstract
High-field electron paramagnetic resonance spectroscopy shows that the structurally distorted Mn<sup>III</sup> ion in Na<sub>5</sub>[Mn(L-tart)<sub>2</sub>]•12H<sub>2</sub>O (1; L-tart = L-tartrate) has a significant negative axial zero-field splitting and a small rhombic anisotropy (∼1% of D). Alternating-current magnetic susceptibility measurements demonstrate that 1, which contains isolated Mn<sup>III</sup> centers, displays slow relaxation of its magnetization under an applied directcurrent magnetic field.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Hill, Prof Stephen and Craig, Dr Gavin and Murrie, Professor Mark |
| Authors: | Craig, G. A., Marbey, J. J., Hill, S., Roubeau, O., Parsons, S., and Murrie, M. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
| Copyright Holders: | Copyright © 2014 The Authors |
| First Published: | First published in Inorganic Chemistry 54(1):13-15 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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