McHugh, P. J., Das, A. K., Wallace, A. G., Kulshrestha, V., Shahi, V. K. and Symes, M. D. (2021) An Investigation of a (vinylbenzyl) trimethylammonium and N-vinylimidazole-substituted poly (vinylidene fluoride-co-hexafluoropropylene) copolymer as an anion-exchange membrane in a lignin-oxidising electrolyser. Membranes, 11(6), 425. (doi: 10.3390/membranes11060425)
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Abstract
Electrolysis is seen as a promising route for the production of hydrogen from water, as part of a move to a wider “hydrogen economy”. The electro-oxidation of renewable feedstocks offers an alternative anode couple to the (high-overpotential) electrochemical oxygen evolution reaction for developing low-voltage electrolysers. Meanwhile, the exploration of new membrane materials is also important in order to try and reduce the capital costs of electrolysers. In this work, we synthesise and characterise a previously unreported anion-exchange membrane consisting of a fluorinated polymer backbone grafted with imidazole and trimethylammonium units as the ion-conducting moieties. We then investigate the use of this membrane in a lignin-oxidising electrolyser. The new membrane performs comparably to a commercially-available anion-exchange membrane (Fumapem) for this purpose over short timescales (delivering current densities of 4.4 mA cm−2 for lignin oxidation at a cell potential of 1.2 V at 70 °C during linear sweep voltammetry), but membrane durability was found to be a significant issue over extended testing durations. This work therefore suggests that membranes of the sort described herein might be usefully employed for lignin electrolysis applications if their robustness can be improved.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Das, Mr Arindam Kumar and Wallace, Mr Alexander and Symes, Professor Mark and McHugh, Mr Patrick |
| Authors: | McHugh, P. J., Das, A. K., Wallace, A. G., Kulshrestha, V., Shahi, V. K., and Symes, M. D. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Membranes |
| Publisher: | MDPI |
| ISSN: | 2077-0375 |
| ISSN (Online): | 2077-0375 |
| Published Online: | 02 June 2021 |
| Copyright Holders: | Copyright © 2021 The Authors |
| First Published: | First published in Membranes 11(6): 425 |
| Publisher Policy: | Reproduced under a Creative Commons License |
| Data DOI: | 10.5525/gla. researchdata.1153 |
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