Jagadamma, L. K., Taylor, R. G.D., Kanibolotsky, A. L., Sajjad, M. T., Wright, I. A., Horton, P. N., Coles, S. J., Samuel, I. D.W. and Skabara, P. J. (2019) Highly efficient fullerene and non-fullerene based ternary organic solar cells incorporating a new tetrathiocin-cored semiconductor. Sustainable Energy and Fuels, 3(8), pp. 2087-2099. (doi: 10.1039/C9SE00343F)
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Abstract
A new dual-chain oligothiophene-based organic semiconductor, EH-5T-TTC, is presented. The molecule contains two conjugated chains linked by a fused tetrathiocin core. X-ray crystallography reveals a boat conformation within the 8-membered sulfur heterocycle core and extensive π–π and intermolecular sulfur–sulfur interactions in the bulk, leading to a 2-dimensional structure. This unusual molecule has been studied as a ternary component in organic solar cell blends containing the electron donor PTB7-Th and both fullerene (PC71BM) and non-fullerene acceptors ITIC and EH-IDTBR. By incorporating EH-5T-TTC as a ternary component, the power conversion efficiency of the binary blends containing non-fullerene acceptor increases by 17% (from 7.8% to 9.2%) and by 85% for the binary blend with fullerene acceptor (from 3.3% to 6.3%). Detailed characterisation of the ternary blend systems implies that the ternary small molecule EH-5T-TTC functions differently in polymer:fullerene and polymer:non-fullerene blends and has dual functions of morphology modification and complementary spectral absorption.
Item Type: | Articles |
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Additional Information: | The authors thank the EPSRC for funding under grants EP/L012200/1 and EP/L012294/1. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Skabara, Professor Peter |
Authors: | Jagadamma, L. K., Taylor, R. G.D., Kanibolotsky, A. L., Sajjad, M. T., Wright, I. A., Horton, P. N., Coles, S. J., Samuel, I. D.W., and Skabara, P. J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Sustainable Energy and Fuels |
Publisher: | Royal Society of Chemistry |
ISSN: | 2398-4902 |
ISSN (Online): | 2398-4902 |
Published Online: | 18 June 2019 |
Copyright Holders: | Copyright © 2019 The Authors |
First Published: | First published in Sustainable Energy and Fuels 3(8): 2087-2099 |
Publisher Policy: | Reproduced under a Creative Commons License |
Data DOI: | 10.5525/gla.researchdata.833 |
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