Rational serendipity: ‘‘undirected’’ synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks

Frost, J. M., Kettles, F. J., Wilson, C. and Murrie, M. (2016) Rational serendipity: ‘‘undirected’’ synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks. Dalton Transactions, 45(45), pp. 18094-18097. (doi: 10.1039/C6DT03914F)

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Abstract

Use of an aminopolyalcohol-based MnII complex in solvothermal CuII chemistry leads to a rare example of a high nuclearity heterometallic {MnIII10CuII5} system, in which four CuII(H1Edte) units trap an inner {MnIII10CuII} oxide core.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Frost, Dr Jamie and Murrie, Professor Mark
Authors: Frost, J. M., Kettles, F. J., Wilson, C., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:28 October 2016
Copyright Holders:Copyright © 2016 The Royal Society of Chemistry
First Published:First published in Dalton Transactions 45(45):18094-18097
Publisher Policy:Reproduced under a Creative Commons License
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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
555881Atom-by-atom control for the targeted chemical synthesis of heterometallic molecular nanomagnetsMark MurrieEngineering & Physical Sciences Research Council (EPSRC)EP/I027203/1CHEM - CHEMISTRY
618561Pressure-tuning interactions in molecule-based magnetsMark MurrieEngineering & Physical Sciences Research Council (EPSRC)EP/K033662/1CHEM - CHEMISTRY