Marshall, R. J., Richards, T., Hobday, C. L., Murphie, C. F., Wilson, C. , Moggach, S. A., Bennett, T. D. and Forgan, R. S. (2016) Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance. Dalton Transactions, 45(10), pp. 4132-4135. (doi: 10.1039/C5DT03178H) (PMID:26583777)
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Abstract
A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to show bromination of unsaturated carbon-carbon bonds in it and an analogous Zr MOF leads to more compliant materials with lower elastic moduli.
| Item Type: | Articles |
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| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire and Forgan, Professor Ross and Marshall, Mr Ross James |
| Authors: | Marshall, R. J., Richards, T., Hobday, C. L., Murphie, C. F., Wilson, C., Moggach, S. A., Bennett, T. D., and Forgan, R. S. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| ISSN (Online): | 1477-9234 |
| Published Online: | 11 November 2015 |
| Copyright Holders: | Copyright © 2016 Royal Society of Chemistry |
| First Published: | First published in Dalton Transactions 45(10): 4132-4135 |
| Publisher Policy: | Reproduced under a Creative Commons License |
| Data DOI: | 10.5525/gla.researchdata.231 |
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