Spectrum imaging of complex nanostructures using DualEELS: I. digital extraction replicas

Bobynko, J., MacLaren, I. and Craven, A. J. (2015) Spectrum imaging of complex nanostructures using DualEELS: I. digital extraction replicas. Ultramicroscopy, 149, pp. 9-20. (doi:10.1016/j.ultramic.2014.10.014)

[img]
Preview
Text
99265.pdf - Published Version
Available under License Creative Commons Attribution Non-commercial No Derivatives.

3MB

Publisher's URL: http://dx.doi.org/10.1016/j.ultramic.2014.10.014

Abstract

This paper shows how it is possible to use Dual Electron Energy Loss Spectroscopy (DualEELS) to digitally extract spectrum images for one phase of interest in a complex nanostructured specimen. The specific cases studied here concern Nb or V precipitates, a few nanometres in size, in high manganese steels. The procedures outlined allow the extraction of the precipitate signal from the Fe–Mn matrix, as well as correction for surface oxide and any surface carbon contamination. The resulting precipitate-only spectrum images are then suitable for quantitative analysis of the precipitate chemistry. This procedure results in much improved background shapes under all edges of interest, mainly as a result of the removal of the extended electron loss fine structure (EXELFS) from the elements in the matrix. This allows the reliable extraction of even tiny quantities of elements, such as low levels of nitrogen in some carbide precipitates. As well as being relevant to precipitation in steels, these techniques will be widely applicable to the separation of chemically-distinct phases in complex nanostructured samples, and can be viewed as a digital version of the extraction replica technique.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Craven, Professor Alan and MacLaren, Dr Ian
Authors: Bobynko, J., MacLaren, I., and Craven, A. J.
College/School:College of Science and Engineering > School of Physics and Astronomy
Journal Name:Ultramicroscopy
Publisher:Elsevier
ISSN:0304-3991
ISSN (Online):1879-2723
Copyright Holders:Copyright © 2014 Elsevier
First Published:First published in Ultramicroscopy 149:9-20
Publisher Policy:Reproduced under a Creative Commons License

University Staff: Request a correction | Enlighten Editors: Update this record