The challenge of storage in the hydrogen energy cycle: nanostructured hydrides as a potential solution

Hanlon, J. M., Reardon, H., Tapia-Ruiz, N. and Gregory, D. H. (2012) The challenge of storage in the hydrogen energy cycle: nanostructured hydrides as a potential solution. Australian Journal of Chemistry, 65(6), pp. 656-671. (doi:10.1071/CH11437)

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Publisher's URL: http://dx.doi.org/10.1071/CH11437

Abstract

Hydrogen has the capacity to provide society with the means to carry ‘green’ energy between the point of generation and the point of use. A sustainable energy society in which a hydrogen economy predominates will require renewable generation provided, for example, by artificial photosynthesis and clean, efficient energy conversion effected, for example, by hydrogen fuel cells. Vital in the hydrogen cycle is the ability to store hydrogen safely and effectively. Solid-state storage in hydrides enables this but no material yet satisfies all the demands associated with storage density and hydrogen release and uptake; particularly for mobile power. Nanochemical design methods present potential routes to overcome the thermodynamic and kinetic hurdles associated with solid state storage in hydrides. In this review we discuss strategies of nanosizing, nanoconfinement, morphological/dimensional control, and application of nanoadditives on the hydrogen storage performance of metal hydrides. We present recent examples of how such approaches can begin to address the challenges and an evaluation of prospects for further development.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Reardon, Miss Hazel and Tapia, Miss Nuria and Hanlon, Dr James and Gregory, Professor Duncan
Authors: Hanlon, J. M., Reardon, H., Tapia-Ruiz, N., and Gregory, D. H.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Australian Journal of Chemistry
Publisher:CSIRO Publishing
ISSN:0004-9425
ISSN (Online):1445-0038
Copyright Holders:Copyright © 2014 The Authors
First Published:First published in Australian Journal of Chemistry 65(6):656-671
Publisher Policy:Reproduced under a Creative Commons License

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
446531SUPERGEN programme renewalDuncan GregoryEngineering & Physical Sciences Research Council (EPSRC)EP/E040071/1CHEM - CHEMISTRY