Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi:10.1039/C3CC49293A)

Full text not currently available from Enlighten.

Publisher's URL: http://dx.doi.org/10.1039/C3CC49293A

Abstract

The one-pot syntheses of a series of dimeric and trimeric selenotungstates based on the [Se2W12O46]12- unit are presented alongside the structure of the tetrameric [Se8W48O176]32- wheel. Mass spectrometry has probed the stability of these clusters whilst their electronic structure has been contrasted to their known phosphotungstate analogues.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Long, Dr Deliang and Vila-Nadal, Dr Laia and Cameron, Mr Jamie and Cronin, Professor Lee and Gao, Miss Jing
Authors: Cameron, J. M., Gao, J., Vila-Nadal, L., Long, D.-L., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X

University Staff: Request a correction | Enlighten Editors: Update this record

Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
503291Molecular-Metal-Oxide-nanoelectronicS (M-MOS): Achieving the Molecular LimitLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/H024107/1CHEM - CHEMISTRY
503295Molecular-Metal-Oxide-nanoelectronicS (M-MOS): Achieving the Molecular LimitLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/H024107/1CHEM - CHEMISTRY
562821Innovative Manufacturing Research Centre for Continuous Manufacturing and Crystallisation (CMAC)Leroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/I033459/1CHEM - CHEMISTRY
577391Programmable Molecular Metal Oxides (PMMOs) - From Fundamentals to ApplicationLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/J015156/1CHEM - CHEMISTRY