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Publisher's URL: http://dx.doi.org/10.1016/S0022-328X(99)00318-6
[Me3PtF]4) can be prepared from the action of AgF on [Me3PtI]4. In the presence of moisture it hydrolyses to give progressively [(Me3PtF)3(Me3PtOH)], [(Me3PtF)2(Me3PtOH)2], [(Me3PtF)(Me3PtOH)3] and [Me3PtOH]4. Variable temperature NMR spectroscopy of these partially hydrolysed tetra-platinum fluorides shows that at higher temperatures the methyl groups within each Me3Pt unit rapidly exchange sites by an intramolecular mechanism, but the cubic Pt4X4 cages retain their integrity.
|Glasgow Author(s) Enlighten ID:||UNSPECIFIED|
|Authors:||Cross, R.J., Haupt, M., Rycroft, D.S., and Winfield, J.M.|
|Subjects:||Q Science > QD Chemistry|
|College/School:||College of Science and Engineering > School of Chemistry|
|Journal Name:||Journal of Organometallic Chemistry|