![[feed]](http://eprints.gla.ac.uk/style/images/feed-icon-14x14.png){kind=icon}
![[feed]](http://eprints.gla.ac.uk/style/images/twitter-logo.png){kind=logo}
Cross, R.J., Haupt, M., Rycroft, D.S., and Winfield, J.M. (1999) Trimethylplatinum hydroxy-fluorides. Journal of Organometallic Chemistry, 587 (2). pp. 195-199. ISSN 0022-328X (doi:10.1016/S0022-328X(99)00318-6)
Full text not currently available from Enlighten.
Publisher's URL: http://dx.doi.org/10.1016/S0022-328X(99)00318-6
Abstract
[Me3PtF]4) can be prepared from the action of AgF on [Me3PtI]4. In the presence of moisture it hydrolyses to give progressively [(Me3PtF)3(Me3PtOH)], [(Me3PtF)2(Me3PtOH)2], [(Me3PtF)(Me3PtOH)3] and [Me3PtOH]4. Variable temperature NMR spectroscopy of these partially hydrolysed tetra-platinum fluorides shows that at higher temperatures the methyl groups within each Me3Pt unit rapidly exchange sites by an intramolecular mechanism, but the cubic Pt4X4 cages retain their integrity.
| Item Type: | Article |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s): | UNSPECIFIED |
| Authors: | Cross, R.J., Haupt, M., Rycroft, D.S., and Winfield, J.M. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Organometallic Chemistry |
| ISSN: | 0022-328X |
University Staff: Request a correction | Enlighten Editors: Update this record
Tools
Tools