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Trimethylplatinum hydroxy-fluorides

Cross, R.J., Haupt, M., Rycroft, D.S., and Winfield, J.M. (1999) Trimethylplatinum hydroxy-fluorides. Journal of Organometallic Chemistry, 587 (2). pp. 195-199. ISSN 0022-328X (doi:10.1016/S0022-328X(99)00318-6)

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Publisher's URL: http://dx.doi.org/10.1016/S0022-328X(99)00318-6

Abstract

[Me3PtF]4) can be prepared from the action of AgF on [Me3PtI]4. In the presence of moisture it hydrolyses to give progressively [(Me3PtF)3(Me3PtOH)], [(Me3PtF)2(Me3PtOH)2], [(Me3PtF)(Me3PtOH)3] and [Me3PtOH]4. Variable temperature NMR spectroscopy of these partially hydrolysed tetra-platinum fluorides shows that at higher temperatures the methyl groups within each Me3Pt unit rapidly exchange sites by an intramolecular mechanism, but the cubic Pt4X4 cages retain their integrity.

Item Type:Article
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:UNSPECIFIED
Authors: Cross, R.J., Haupt, M., Rycroft, D.S., and Winfield, J.M.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Organometallic Chemistry
ISSN:0022-328X

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