Six-membered electron transfer series [V(dithiolene)3]z (z = 1+, 0, 1-, 2-, 3-, 4-). An X-ray absorption spectroscopic and density functional theoretical study

Sproules, S. , Weyhermüller, T., DeBeer, S. and Wieghardt, K. (2010) Six-membered electron transfer series [V(dithiolene)3]z (z = 1+, 0, 1-, 2-, 3-, 4-). An X-ray absorption spectroscopic and density functional theoretical study. Inorganic Chemistry, 49(11), pp. 5241-5261. (doi:10.1021/ic100344f)

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Abstract

Three members of the electron transfer series [V(dithiolene)3]z (z = 1+, 0, 1−, 2−, 3−, 4-) have been probed by vanadium and sulfur K-edge X-ray absorption spectroscopy. A V(IV) central ion exists for the neutral, monoanionic, and dianionic species that are interrelated by ligand-centered redox processes. Oxidized ligands are essential for a trigonal prismatic geometry in this series, whereas more reduced members are octahedral.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Sproules, S., Weyhermüller, T., DeBeer, S., and Wieghardt, K.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X

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