Arumugam, K., Shaw, M. C., Mague, J. T., Bill, E., Sproules, S. and Donahue, J. P. (2011) Long-range spin coupling: a tetraphosphine-bridged palladium dimer. Inorganic Chemistry, 50(7), pp. 2995-3002. (doi: 10.1021/ic102493g)
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Abstract
Two palladium monodithiolene units are linked by an insulating tetraphosphinobenzene ligand. This neutral compound can be reversibly two-electron oxidized to a dicationic compound formulated as [(adt·)PdII(μ-tpbz)PdII(adt·)]2+. The degenerate ground state leads to a spin-triplet EPR spectrum that is defined by an amazingly small zero-field splitting derived from weak dipolar coupling between the remote dithiolene radicals bridged by the insulating tetraphosphine unit.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
| Authors: | Arumugam, K., Shaw, M. C., Mague, J. T., Bill, E., Sproules, S., and Donahue, J. P. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
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