Paramagnetic oxotungsten(V) complexes containing the hydrotris(3,5-dimethylpyrazol-1-yl)borate ligand

Sproules, S. , Eagle, A. A., Taylor, M. K., Gable, R. W., White, J. M. and Young, C. G. (2011) Paramagnetic oxotungsten(V) complexes containing the hydrotris(3,5-dimethylpyrazol-1-yl)borate ligand. Inorganic Chemistry, 50(10), pp. 4503-4514. (doi:10.1021/ic200161m)

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Abstract

An extensive series of oxotungsten(V) complexes of the general formula Tp*WOXY, where Tp* is hydrotris(3,5-dimethylpyrazol-1-yl)borate and X, Y = monodentate or XY = bidentate O-, S-, or Se-donor ligands, have been prepared. The series is characterized by spectroscopy, electrochemistry, and X-ray crystallography. The reduction of Tp*WO(qdt) (qdt = quinoxaline-2,3-dithiolate) in acidic media gave rise to unusually intense low-energy absorption bands.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Sproules, S., Eagle, A. A., Taylor, M. K., Gable, R. W., White, J. M., and Young, C. G.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X

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