Sproules, S. , Eagle, A. A., Taylor, M. K., Gable, R. W., White, J. M. and Young, C. G. (2011) Paramagnetic oxotungsten(V) complexes containing the hydrotris(3,5-dimethylpyrazol-1-yl)borate ligand. Inorganic Chemistry, 50(10), pp. 4503-4514. (doi: 10.1021/ic200161m)
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Abstract
An extensive series of oxotungsten(V) complexes of the general formula Tp*WOXY, where Tp* is hydrotris(3,5-dimethylpyrazol-1-yl)borate and X, Y = monodentate or XY = bidentate O-, S-, or Se-donor ligands, have been prepared. The series is characterized by spectroscopy, electrochemistry, and X-ray crystallography. The reduction of Tp*WO(qdt) (qdt = quinoxaline-2,3-dithiolate) in acidic media gave rise to unusually intense low-energy absorption bands.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
Authors: | Sproules, S., Eagle, A. A., Taylor, M. K., Gable, R. W., White, J. M., and Young, C. G. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Inorganic Chemistry |
Publisher: | American Chemical Society |
ISSN: | 0020-1669 |
ISSN (Online): | 1520-510X |
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