Sproules, S. , Banerjee, P., Weyhermüller, T., Yan, Y., Donahue, J. P. and Wieghardt, K. (2011) Monoanionic molybdenum and tungsten tris(dithiolene) complexes: a multifrequency EPR study. Inorganic Chemistry, 50(15), pp. 7106-7122. (doi: 10.1021/ic2006265)
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Abstract
The electronic structures of molybdenum and tungsten tris(dithiolene) monoanions have been investigated by multifrequency EPR. The outcome details a ligand-type dependent ground state description, with a ligand-centered paramagnet resulting from systems with olefinic dithiolenes, whereas aromatic dithiolenes find the unpaired electron on the metal. These results are complementary with sulfur K-edge XAS studies.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
Authors: | Sproules, S., Banerjee, P., Weyhermüller, T., Yan, Y., Donahue, J. P., and Wieghardt, K. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Inorganic Chemistry |
Publisher: | American Chemical Society |
ISSN: | 0020-1669 |
ISSN (Online): | 1520-510X |
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