Monoanionic molybdenum and tungsten tris(dithiolene) complexes: a multifrequency EPR study

Sproules, S. , Banerjee, P., Weyhermüller, T., Yan, Y., Donahue, J. P. and Wieghardt, K. (2011) Monoanionic molybdenum and tungsten tris(dithiolene) complexes: a multifrequency EPR study. Inorganic Chemistry, 50(15), pp. 7106-7122. (doi:10.1021/ic2006265)

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Abstract

The electronic structures of molybdenum and tungsten tris(dithiolene) monoanions have been investigated by multifrequency EPR. The outcome details a ligand-type dependent ground state description, with a ligand-centered paramagnet resulting from systems with olefinic dithiolenes, whereas aromatic dithiolenes find the unpaired electron on the metal. These results are complementary with sulfur K-edge XAS studies.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Sproules, S., Banerjee, P., Weyhermüller, T., Yan, Y., Donahue, J. P., and Wieghardt, K.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X

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