Sproules, S. , Weyhermüller, T., Goddard, R. and Wieghardt, K. (2011) The rhenium tris(dithiolene) electron transfer series: calibrating covalency. Inorganic Chemistry, 50(24), pp. 12623-12631. (doi: 10.1021/ic2016534)
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Abstract
The electronic structure of four members of the electron transfer series [Re(L3)]z (z = 1+, 0, 1−, 2−) have been elucidated by sulfur K-edge X-ray absorption spectroscopy. Two methods of estimating the covalency have been applied and contrasted: determination of the radial dipole integral and TD-DFT calculation of the pre-edge transitions. The analysis is extended to vanadium and molybdenum analogues affording a more precise description of the neutral complex of the latter series.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
| Authors: | Sproules, S., Weyhermüller, T., Goddard, R., and Wieghardt, K. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
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