The rhenium tris(dithiolene) electron transfer series: calibrating covalency

Sproules, S. , Weyhermüller, T., Goddard, R. and Wieghardt, K. (2011) The rhenium tris(dithiolene) electron transfer series: calibrating covalency. Inorganic Chemistry, 50(24), pp. 12623-12631. (doi:10.1021/ic2016534)

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Abstract

The electronic structure of four members of the electron transfer series [Re(L3)]z (z = 1+, 0, 1−, 2−) have been elucidated by sulfur K-edge X-ray absorption spectroscopy. Two methods of estimating the covalency have been applied and contrasted: determination of the radial dipole integral and TD-DFT calculation of the pre-edge transitions. The analysis is extended to vanadium and molybdenum analogues affording a more precise description of the neutral complex of the latter series.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Sproules, Dr Stephen
Authors: Sproules, S., Weyhermüller, T., Goddard, R., and Wieghardt, K.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
Publisher:American Chemical Society
ISSN:0020-1669
ISSN (Online):1520-510X

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