A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C., Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi:10.1039/c3cc45659e)

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Abstract

The new tungstatoiodate, α-[H5W18O59(IO3)]6−, containing IVO3− within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)]6− by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I–O covalent bonds are broken.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Busche, Dr Christoph and Yan, Mr Jun and Moiras, Dr Charalampos and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Long, D.L., Yan, J., Ruiz De La Oliva, A., Busche, C., Miras, H.N., Errington, R.J., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X

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