Malkov, A.V., Kysilka, O., Edgar, M., Kadlčíková, A., Kotora, M. and Kocovsky, P. (2011) A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans. Chemistry: A European Journal, 17(26), pp. 7162-7166. (doi: 10.1002/chem.201100513)
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Abstract
Three for the price of two: A bifunctional allyldisilane undergoes a two-step triple allylation sequence with pairs of aldehydes to give all-cis trisubstituted tetrahydrofurans in excellent enantio- and diastereoselectivity (see scheme). The first allylation step, which sets up the key stereogenic.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Malkov, Dr Andrei and Edgar, Dr Matthew and Kocovsky, Professor Pavel |
| Authors: | Malkov, A.V., Kysilka, O., Edgar, M., Kadlčíková, A., Kotora, M., and Kocovsky, P. |
| College/School: | College of Science and Engineering > School of Chemistry College of Science and Engineering > School of Physics and Astronomy |
| Journal Name: | Chemistry: A European Journal |
| Journal Abbr.: | Chem. Eur J. |
| ISSN: | 0947-6539 |
| ISSN (Online): | 1521-3765 |
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