Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) A general route for the transfer of large, highly-charged polyoxometalates from aqueous to organic phase. Polyhedron, 52, pp. 159-164. (doi: 10.1016/j.poly.2012.10.015)
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Abstract
A new mixed solvent procedure which allows the exchange of polyoxometalate (POM) alkali metal cations for tetrabutylammonium (TBA) and protons is presented. This method has been demonstrated for simple Keggin PW12O40](3-) and Dawson P2W18O62](6-) POMs as well as the larger phosphotungstates Na subset of P5W30O110](14-) and K-4 subset of P8W48O184](36-) for which no TBA salt has been previously reported.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Gabb, Mr David and Boyd, Mr Thomas and Mitchell, Mr Scott and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Gabb, D., Pradeep, C. P., Boyd, T., Mitchell, S. G., Miras, H. N., Long, D.-L., and Cronin, L. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry College of Science and Engineering > School of Engineering > Autonomous Systems and Connectivity |
Journal Name: | Polyhedron |
Publisher: | Elsevier |
ISSN: | 0277-5387 |
ISSN (Online): | 1873-3719 |
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