Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions

Zang, H., Chen, J.-J., Long, D.-L. , Cronin, L. and Miras, H. N. (2013) Assembly of thiometalate-based [Mo16] and [Mo36] composite clusters combining [Mo2O2S2],2+ cations and selenite anions. Advanced Materials, 25(43), pp. 6245-6249. (doi:10.1002/adma.201302565)

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Publisher's URL: http://dx.doi.org/10.1002/adma.201302565

Abstract

A new family of thiometalate-based composite molecular materials is synthesized and characterized. The 1.6 and 1.9 nm sized clusters are observed in the gas phase utilizing high resolution ESI-MS. The diversity of the selenite anions as inorganic ligand is demonstrated by the isolation of the highest nuclearity selenium-based oxothiometalate materials reported so far. The observed proton conductivity of the selenite based oxothiometalate species render them as promising alternative materials for fuel cell applications.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Long, Dr Deliang and Cronin, Professor Lee
Authors: Zang, H., Chen, J.-J., Long, D.-L., Cronin, L., and Miras, H. N.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Advanced Materials
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:0935-9648
ISSN (Online):1521-4095

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