Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents

Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D. and Cronin, L. (2013) Quick and selective synthesis of Li6[α-P2W18O62]·28H2O soluble in various organic solvents. Dalton Transactions, 42, pp. 11363-11366. (doi:10.1039/c3dt51120k)

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Abstract

Herein we report the synthesis of α-Dawson type POM, Li6[α-P2W18O62]·28H2O, directly from the use of Li2WO4 as the tungstate source. The salt obtained was soluble not only in water but also in a range of polar and non-polar organic solvents, such as benzene.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Tsunashima, Dr Ryo and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Kato, C., Nishihara, S., Tsunashima, R., Tatewaki, Y., Okada, S., Ren, X.M., Inoue, K., Long, D., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234

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