Albada, H.B., Soulimani, F., Jacobs, H.J.F., Versluis, C., Weckhuysen, B.M. and Liskamp, R.M.J. (2012) Triazacyclophane (TAC)-scaffolded histidine and aspartic acid residues as mimics of non-heme metalloenzyme active sites. Organic and Biomolecular Chemistry, 10(5), pp. 1088-1092. (doi: 10.1039/c1ob06806g)
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Abstract
We describe the synthesis and coordination behaviour to copper(II) of two close structural triazacyclophane-based mimics of two often encountered aspartic acid and histidine containing metalloenzyme active sites. Coordination of these mimics to copper(I) and their reaction with molecular oxygen leads to the formation of dimeric bis(μ-hydroxo) dicopper(II) complexes.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Liskamp, Professor Robert |
Authors: | Albada, H.B., Soulimani, F., Jacobs, H.J.F., Versluis, C., Weckhuysen, B.M., and Liskamp, R.M.J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Organic and Biomolecular Chemistry |
ISSN: | 1477-0520 |
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