Clark, S. , Yang, G. and Osnowski, A. (2013) Synthesis of the C‑1-C-17 fragment of amphidinolides C, C2, C3, and F. Organic Letters, 15(7), pp. 1460-1463. (doi: 10.1021/ol4004838)
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Abstract
The C-1-C-17 fragment of amphidinolides C, C2, C3, and F has been constructed from a trans-2,5-disubstituted dihydrofuranone prepared by diastereoselective rearrangement of a free or metal-bound oxonium ylide generated from a metal carbenoid. The dihydrofuranone was converted into an aldehyde corresponding to the C-1-C-8 framework, and this was coupled to the C-9-C-17 unit by nucleophilic addition of a vinylic anion
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Clark, Professor Stephen |
Authors: | Clark, S., Yang, G., and Osnowski, A. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Research Group: | Clark Research Group |
Journal Name: | Organic Letters |
Journal Abbr.: | Org. Lett. |
ISSN: | 1523-7060 |
ISSN (Online): | 1523-7052 |
Published Online: | 25 March 2013 |
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