Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates

Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi:10.1039/c2cc34865a)

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Abstract

Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a {Co9[P2W15]3} and {Co14[P2W15]4} (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Symes, Dr Mark and Lydon, Miss Claire and Murrie, Professor Mark and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Lydon, C., Sabi, M.M., Symes, M.D., Long, D.L., Murrie, M., Yoshii, S., Nojiri, H., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
ISSN:1359-7345
Published Online:30 August 2012

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