Lydon, C., Sabi, M.M., Symes, M.D. , Long, D.L. , Murrie, M. , Yoshii, S., Nojiri, H. and Cronin, L. (2012) Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates. Chemical Communications, 48(79), pp. 9819-9821. (doi: 10.1039/c2cc34865a)
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Abstract
Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a {Co9[P2W15]3} and {Co14[P2W15]4} (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Symes, Professor Mark and Lydon, Miss Claire and Murrie, Professor Mark and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Lydon, C., Sabi, M.M., Symes, M.D., Long, D.L., Murrie, M., Yoshii, S., Nojiri, H., and Cronin, L. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
ISSN: | 1359-7345 |
Published Online: | 30 August 2012 |
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