Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-)

Miras, H.N. , Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A. and Cronin, L. (2008) Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-). Chemical Communications(39), pp. 4703-4705. (doi:10.1039/B811279G)

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Abstract

A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, Mo(11)(VI)V(5)(V)V(2)(IV)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Charalampos and Cronin, Professor Leroy
Authors: Miras, H.N., Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:15 September 2008

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