Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi:10.1002/anie.201002672)

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Abstract

Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is “alloyed” with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each discrete network, leading to a series of single-crystalline mixed transition-metal frameworks with novel redox properties.

Item Type:Articles
Keywords:alloys, framework materials, polyoxometalates, redox chemistry
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Thiel, Mr Johannes and Moiras, Dr Charalampos and Rosnes, Dr Mali and Boyd, Mr Thomas and Ritchie, Mr Christopher and Long, Dr De Liang and Cronin, Professor Leroy and Streb, Mr Carsten
Authors: Thiel, J., Ritchie, C., Miras, H.N., Streb, C., Mitchell, S.G., Boyd, T., Ochoa, M.N.C., Rosnes, M., McIvet, J., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3757
Published Online:14 July 2010

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