Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV)

Li, F., Long, D.L. , Cameron, J.M., Miras, H.N. , Pradeep, C., Xu, L. and Cronin, L. (2012) Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(IV). Dalton Transactions, 41(33), pp. 9859-9862. (doi:10.1039/C2DT30627A)

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Abstract

The heteropolyvanadate cluster (n-C4H9)(4)N](4)(MnV12O34)-V-IV]center dot 2CH(3)CN has been isolated by cation exchange from K-10-((MnV11O32)-V-IV)(2)]center dot 20H(2)O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Cameron, Mr Jamie and Long, Dr Deliang and Cronin, Professor Lee
Authors: Li, F., Long, D.L., Cameron, J.M., Miras, H.N., Pradeep, C., Xu, L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Publisher:Royal Society of Chemistry
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:04 May 2012

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