Miras, H.N. , Sorus, M., Hawkett, J., Sells, D.O., McInnes, E.L. and Cronin, L. (2012) Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation. Journal of the American Chemical Society, 134(16), pp. 6980-6983. (doi: 10.1021/ja302861z)
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Abstract
The redox-controlled driven oscillatory template exchange between phosphate (P) and vanadate (V) anions enclosed in an {X2M18} cluster is reported. Extensive investigations using a range of techniques, including correlated ESI-MS, EPR, and UV-vis as a function of reaction time, showed that six complete oscillations interconverting the capsule species present in solution from {P2M18} to {V2M18} were possible, provided that a sufficient concentration of the TEA reducing agent was present in solution.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Cronin, Professor Lee |
| Authors: | Miras, H.N., Sorus, M., Hawkett, J., Sells, D.O., McInnes, E.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of the American Chemical Society |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| ISSN (Online): | 1520-5126 |
| Published Online: | 09 April 2012 |
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