Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

Roach, B.D., Forgan, R.S. , Tasker, P.A., Swart, R.M., Campbell, J., McAllister, F.E., Stopford, A.P. and Duncombe, B.J. (2010) Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes. Dalton Transactions, 39(24), pp. 5614-5616. (doi:10.1039/C003135F)

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Abstract

Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Forgan, Dr Ross
Authors: Roach, B.D., Forgan, R.S., Tasker, P.A., Swart, R.M., Campbell, J., McAllister, F.E., Stopford, A.P., and Duncombe, B.J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:19 May 2010

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