Bates, G.W., Davidson, J.E., Forgan, R.S. , Gale, P.A., Henderson, D.K., King, M.G., Light, M.E., Moore, S.J., Tasker, P.A. and Tong, C.C. (2012) A dual host approach to NiSO4 extraction. Supramolecular Chemistry, 24(2), pp. 117-126. (doi: 10.1080/10610278.2011.631706)
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Abstract
This paper reports the synthesis of sulphate extractants, N,N'-bis-(2-dibutylamino-ethyl)-isophthalamide (1), pyridine-2,6-dicarboxylic acid bis-[(2-dibutylamino-ethyl)-amide] (2) and 3,4-diphenyl-1H-pyrrole-2,5-dicarboxylic acid bis-[(2-dibutylamino-ethyl)-amide] (3), and demonstrates that, in combination with a commercially available oxime extractant 2-hydroxy-5-nonyl benzaldehyde oxime (P50), these dual host systems are better extractants for nickel(II) sulphate than the metal salt extractant, 5-nonyl-3-dihexylaminomethyl-2-hydroxy-benzaldehyde oxime (4).
| Item Type: | Articles |
|---|---|
| Additional Information: | Special Issue: Special issue dedicated to the Sixth International Symposium on Macrocyclic and Supramolecular Chemistry (6-ISMSC) |
| Keywords: | anion binding, extraction, hydrometallurgy, hydrogen bonding |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Forgan, Professor Ross |
| Authors: | Bates, G.W., Davidson, J.E., Forgan, R.S., Gale, P.A., Henderson, D.K., King, M.G., Light, M.E., Moore, S.J., Tasker, P.A., and Tong, C.C. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Supramolecular Chemistry |
| Publisher: | Taylor and Francis |
| ISSN: | 1061-0278 |
| ISSN (Online): | 1029-0478 |
| Published Online: | 11 November 2011 |
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