Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates”

Lincheneau, C., Destribats, C., Barry, D.E., Kitchen, J.A., Peacock, R.D. and Gunnlaugsson, T. (2011) Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates”. Dalton Transactions, 40(45), pp. 12056-12059. (doi: 10.1039/c1dt11225b)

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Abstract

The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH(3)CN give rise to the formation of lanthanide luminescent 'half-helicates' in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Peacock, Dr Robert
Authors: Lincheneau, C., Destribats, C., Barry, D.E., Kitchen, J.A., Peacock, R.D., and Gunnlaugsson, T.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
ISSN:1477-9226
Published Online:22 September 2011

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