Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates

Lydon, C., Busche, C., Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi:10.1002/anie.201105829)

Lydon, C., Busche, C., Miras, H.N. , Delf, A., Long, D.-L. , Yellowlees, L. and Cronin, L. (2012) Nanoscale growth of molecular oxides: assembly of a {V6} double cubane between two lacunary {P2W15} polyoxometalates. Angewandte Chemie (International Edition), 51(9), pp. 2115-2118. (doi:10.1002/anie.201105829)

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Publisher's URL: http://dx.doi.org/10.1002/anie.201105829

Abstract

POM-in-POM: A Wells–Dawson polyoxometalate sandwich compound with a double cubane core consisting of six vanadium atoms has been synthesized (see structure). Cluster formation was followed by mass spectrometry and the reduction of the double cubane was studied by a novel technique combining mass spectrometry and spectroelectrochemistry.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Busche, Dr Christoph and Moiras, Dr Charalampos and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Lydon, C., Busche, C., Miras, H.N., Delf, A., Long, D.-L., Yellowlees, L., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew. Chem. Int. Ed. Engl.
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:01 February 2012

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