Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi: 10.1002/anie.201108428)
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Abstract
Neoclassical architecture: A new family of heteropolyoxometalates with “pagoda”-shaped building blocks [Te<sub>n</sub>W<sub>6n+3</sub>O<sub>21n+12</sub>]<sup>(6+2n)−</sup> (n=1, 2, 3) was discovered by adding {TeW<sub>6</sub>O<sub>21</sub>} layers on a classic {TeW<sub>9</sub>O<sub>33</sub>} fragment. Linking of the units allowed the generation of nanostructured clusters whose gross conformation is cation controlled. Studies of the redox behaviors of the multi-layered clusters indicate that the Te<sup>IV</sup> template is redox-active.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Yan, Mr Jun and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Gao, J., Yan, J., Beeg, S., Long, D.L., and Cronin, L. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1433-7851 |
| Published Online: | 28 February 2012 |
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