Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules

Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi:10.1021/ic200943s)

Full text not currently available from Enlighten.

Publisher's URL: http://dx.doi.org/10.1021/ic200943s

Abstract

Vanadate(V)-templated Dawson-type capsules {(VIVMVI17(VO4)2} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM17}-type shell, which was corroborated by EPR and theoretical studies.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Charalampos and Long, Dr De Liang and Cronin, Professor Leroy
Authors: Miras, H.N., Stone, D., Long, D.L., McInnes, E.J.L., Kögerler, P., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
ISSN:0020-1669
ISSN (Online):1520-510X
Published Online:27 July 2011

University Staff: Request a correction | Enlighten Editors: Update this record