Miras, H.N. , Stone, D., Long, D.L. , McInnes, E.J.L., Kögerler, P. and Cronin, L. (2011) Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules. Inorganic Chemistry, 50(17), pp. 8384-8391. (doi: 10.1021/ic200943s)
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Publisher's URL: http://dx.doi.org/10.1021/ic200943s
Abstract
Vanadate(V)-templated Dawson-type capsules {(V<sup>IV</sup>M<sup>VI</sup><sub>17</sub>(VO<sub>4</sub>)<sub>2</sub>} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM<sub>17</sub>}-type shell, which was corroborated by EPR and theoretical studies.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Miras, H.N., Stone, D., Long, D.L., McInnes, E.J.L., Kögerler, P., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
| Published Online: | 27 July 2011 |
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