[Mn6] under pressure: a combined crystallographic and magnetic study

Prescimone, A. et al. (2008) [Mn6] under pressure: a combined crystallographic and magnetic study. Angewandte Chemie, 120(15), pp. 2870-2873. (doi:10.1002/ange.200705819)

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Abstract

Folding under pressure: Crystallographic studies on a Mn6 single-molecule magnet under high pressure conditions show the drastic structural changes of the magnetic core (see picture, Mn purple, O red, N blue), which impact on the magnetic properties of ferromagnetic exchange between the metal atoms will be in booster weaker, and under extremely high pressure, a transition to antiferromagnetic behavior.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Murrie, Professor Mark
Authors: Prescimone, A., Milios, C.J., Moggach, S., Warren, J.E., Lennie, A.R., Sanchez-Benitez, J., Kamenev, K., Bircher, R., Murrie, M., Parsons, S., and Brechin, E.K.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie
ISSN:0044-8249
ISSN (Online):1521-3757
Published Online:05 March 2008

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
399981The effect of high pressure on single-molecule magnetsMark MurrieEngineering & Physical Sciences Research Council (EPSRC)EP/D503752/1Chemistry