Divergent approach to the polymaxenolide and pinnaic acid cores

Ferrari, F.D., Ledgard, A.J. and Marquez, R. (2011) Divergent approach to the polymaxenolide and pinnaic acid cores. Tetrahedron, 67(27-28), pp. 4988-4994. (doi: 10.1016/j.tet.2011.04.047)

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Publisher's URL: http://dx.doi.org/10.1016/j.tet.2011.04.047

Abstract

The divergent syntheses of the spirocyclic pyran core of polymaxenolide and the spirocyclic piperidine core of pinnaic acid have been achieved. Our divergent approach takes advantage of highly efficient Achmatowicz and aza-Achmatowicz rearrangements to generate the highly functionalised cores, which are then regioselectively modified.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Marquez, Dr Rudi and Ferrari, Mr Frank
Authors: Ferrari, F.D., Ledgard, A.J., and Marquez, R.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Tetrahedron
ISSN:0040-4020
Published Online:20 April 2011

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