18O/16O and V/Cr ratios in gem tsavorites from the Neoproterozoic Mozambique metamorphic belt: a clue towards their origins?

Giuliani, G., Fallick, A.E., Feneyrol, J., Ohnenstetter, D., Pardieu, V. and Saul, M. (2011) 18O/16O and V/Cr ratios in gem tsavorites from the Neoproterozoic Mozambique metamorphic belt: a clue towards their origins? Mineralium Deposita, 46(7), pp. 671-676. (doi: 10.1007/s00126-011-0355-6)

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Publisher's URL: http://dx.doi.org/10.1007/s00126-011-0355-6

Abstract

The combination of oxygen isotope composition with V–Cr–Mn trace element concentrations of V-bearing garnets (tsavorites) originating from the main deposits of the Neoproterozoic Mozambique Metamorphic Belt is reported for the first time. The database enables the identification of the geological and geographical sources of the main productive areas from northern and southern Tanzania, Kenya, and Madagascar. Three consistent sets of δ<sup>18</sup>O values between 9.5‰ and 11.0‰, 11.6‰ and 14.5‰, and 15.5‰ and 21.1‰ have been recognized for primary deposits hosted in graphitic gneisses related to the Neoproterozic metasedimentary series. The δ<sup>18</sup>O value of tsavorite is a good tracer of the environment of its formation; the δ<sup>18</sup>O of the fluid in equilibrium with tsavorite was buffered by the host rock during metamorphism and fluid-rock interaction. This study is a first step in characterizing the geochemistry of gem tsavorite from most of the deposits and occurrences worldwide.

Item Type:Articles (Letter)
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Fallick, Professor Anthony
Authors: Giuliani, G., Fallick, A.E., Feneyrol, J., Ohnenstetter, D., Pardieu, V., and Saul, M.
College/School:College of Science and Engineering > Scottish Universities Environmental Research Centre
Journal Name:Mineralium Deposita
Publisher:Springer
ISSN:0026-4598
ISSN (Online):1432-1866
Published Online:15 May 2011

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