Price, D.J., Richardson, T. and Bruce, D.W. (1995) An investigation of the hydrogen bonding in liquid crystal systems using variable-temperature electronic spectroscopy. Journal of the Chemical Society: Chemical Communications, 1995(18), pp. 1911-1912. (doi: 10.1039/C39950001911)
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Abstract
Variable-temperature electronic spectroscopy on the mesomorphic hydrogen-bonded complex between 4-decyloxy-4′-stilbazole and 2,4-dinitrophenol shows that the higher energy ionic hydrogen-bonded state corresponding to proton transfer is significantly populated through the mesophase, and the mesophase provides an additional stabilisation for this state, by virtue of its microscopic structure; the clearing of the smectic A phase is shown not to be driven by hydrogen-bond rupture.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Price, Dr Daniel |
Authors: | Price, D.J., Richardson, T., and Bruce, D.W. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the Chemical Society: Chemical Communications |
Journal Abbr.: | J. Chem. Soc., Chem. Commun. |
Publisher: | Royal Society of Chemistry |
ISSN: | 0022-4936 |
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