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Barnett, N.D.R., Clegg, W., Horsburgh, L., Lindsay, D., Liu, Q.-Y., Mackenzie, F.M., Mulvey, R.E., and Williard, P.G. (1996) Novel octameric structure of the lithium primary amide [{ButN(H)Li}8] and its implication for the directed synthesis of heterometallic imide cages. Chemical Communications (20). pp. 2321-2322. ISSN 1359-7345 (doi:10.1039/CC9960002321)
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Publisher's URL: http://dx.doi.org/10.1039/CC9960002321
Abstract
The crystalline lithium primary amide derived from tert-butylamine, [{ButN(H)Li}n], is structurally characterised by an X-ray diffraction study and shown to be a novel octameric (n= 8) ladder conformation, the cyclic, ‘double-crown’ nature of which implies molecules of this design could direct the synthesis of heterobimetallic (i.e. lithium and another metal) imide cage constructions.
| Item Type: | Article |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s): | Lindsay, Dr David |
| Authors: | Barnett, N.D.R., Clegg, W., Horsburgh, L., Lindsay, D., Liu, Q.-Y., Mackenzie, F.M., Mulvey, R.E., and Williard, P.G. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Journal Abbr.: | Chem. Comm. |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 1996 |
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