Kerr, W.J., Lindsay, D., Rankin, E.M., Scott, J.S. and Watson, S.P. (2000) The brucine N-oxide promoted asymmetric Pauson-Khand reaction. Tetrahedron Letters, 41(17), pp. 3229-3233. (doi: 10.1016/S0040-4039(00)00357-9)
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Publisher's URL: http://dx.doi.org/10.1016/S0040-4039(00)00357-9
Abstract
The brucine <i>N</i>-oxide-mediated asymmetric Pauson–Khand reaction has been further investigated. It was found that the best levels of enantioselection were obtained with substituted propargylic alcohol complexes. The studies also revealed that when acetone or 1,2-dimethoxyethane is used as the reaction solvent, enhanced levels of enantioselectivity, up to an enantiomeric ratio of 11:89, are achieved.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Lindsay, Dr David and Kerr, Professor William |
| Authors: | Kerr, W.J., Lindsay, D., Rankin, E.M., Scott, J.S., and Watson, S.P. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Tetrahedron Letters |
| ISSN: | 0040-4039 |
| Published Online: | 01 January 2000 |
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