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High loading polymer-supported N-Methylmorpholine N-Oxide; a practically efficient and readily recyclable promoter of the Pauson-Khand reaction

Brown, D.S., Campbell, E., Kerr, W.J., Lindsay, D., Morrison, A.J., Pike, K.G., and Watson, S.P. (2000) High loading polymer-supported N-Methylmorpholine N-Oxide; a practically efficient and readily recyclable promoter of the Pauson-Khand reaction. Synlett (11). pp. 1573-1576. ISSN 0936-5214 (doi:10.1055/s-2000-7932)

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Publisher's URL: http://dx.doi.org/10.1055/s-2000-7932

Abstract

A high loading polymer supported amine N-oxide has been prepared and shown to be a good, practicable, and readily recyclable promoter of the Pauson-Khand reaction under mild conditions, generally affording excellent yields of cyclopentenones. In addition, use of N-phenylsulfonyl oxaziridine as a co-oxidant allows use of reduced quantities of the readily available parent polymer-supported amine without the need for prior oxidation of the resin.

Item Type:Article
Status:Published
Refereed:Yes
Glasgow Author(s):Lindsay, Dr David and Kerr, Prof William
Authors: Brown, D.S., Campbell, E., Kerr, W.J., Lindsay, D., Morrison, A.J., Pike, K.G., and Watson, S.P.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Synlett
ISSN:0936-5214
ISSN (Online):1437-2096
Published Online:2000

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