Kennedy, A.R., Kerr, W.J., Lindsay, D., Scott, J.S., and Watson, S.P. (2000) Stereochemical and mechanistic features of asymmetric Pauson-Khand processes. Journal of the Chemical Society: Perkin Transactions 1(24), pp. 4366-4372. (doi:10.1039/b006523o)
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Publisher's URL: http://dx.doi.org/10.1039/b006523o
The absolute stereochemical configurations of a series of optically pure alkyne–Co2(CO)5PPh3 complexes and their corresponding cyclopentenones, derived from Pauson–Khand reaction with norbornene, have been established; an X-ray crystal structure of an optically pure cyclopentenone has facilitated this study. In turn, this has led to the unambiguous determination of the site of decarbonylation and alkene complexation when such monophosphine complexes are utilised in asymmetric Pauson–Khand processes.
|Glasgow Author(s) Enlighten ID:||Lindsay, Dr David and Kerr, Professor William|
|Authors:||Kennedy, A.R., Kerr, W.J., Lindsay, D., Scott, J.S., and Watson, S.P.|
|College/School:||College of Science and Engineering > School of Chemistry|
|Journal Name:||Journal of the Chemical Society: Perkin Transactions 1|
|Publisher:||Royal Society of Chemistry|
|Published Online:||01 January 2000|