A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands

Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi:10.1002/anie.201102727)

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Abstract

The title compound contains an embedded mixed-valence {Mn5O6} cubane core, which is structurally similar to the active site in photosystem II. Solid-, solution-, and gas-phase studies indicate the presence of three lacunary Keggin fragments, thereby giving insight into the complex solution chemistry of plenary POM fragments.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Cogdell, Professor Richard and Moiras, Dr Haralampos and Long, Dr Deliang and Cooper, Dr Geoff and Winter, Mr Ross and Cronin, Professor Lee and Khanra, Dr Sumit
Authors: Mitchell, S. G., Molina, P. I., Khanra, S., Miras, H. N., Prescimone, A., Cooper, G. J.T., Winter, R. W., Brechin, E. K., Long, D., Cogdell, R. J., and Cronin, L.
College/School:College of Medical Veterinary and Life Sciences > Institute of Molecular Cell and Systems Biology
College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:24 August 2011

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