Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry

Wilson, E.F., Miras, H.N. , Rosnes, M.H. and Cronin, L. (2011) Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry. Angewandte Chemie (International Edition), 50(16), pp. 3720-3724. (doi:10.1002/anie.201006938)

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Publisher's URL: http://dx.doi.org/10.1002/anie.201006938

Abstract

Electrospray ionization mass spectrometry (ESI-MS) allows monitoring of the real-time, “in-solution” formation of an organic–inorganic polyoxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese-Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α-Mo<sub>8</sub>O<sub>26</sub>]<sup>4−</sup> cluster in the presence of Mn(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>.

Item Type:Articles
Keywords:Manganese, mass spectrometry, polyoxometalates, self-assembly
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Cronin, Professor Lee
Authors: Wilson, E.F., Miras, H.N., Rosnes, M.H., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew Chem Int Ed Engl
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:24 March 2011
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