Wilson, E.F., Miras, H.N. , Rosnes, M.H. and Cronin, L. (2011) Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry. Angewandte Chemie (International Edition), 50(16), pp. 3720-3724. (doi: 10.1002/anie.201006938)
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Publisher's URL: http://dx.doi.org/10.1002/anie.201006938
Abstract
Electrospray ionization mass spectrometry (ESI-MS) allows monitoring of the real-time, “in-solution” formation of an organic–inorganic polyoxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese-Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α-Mo<sub>8</sub>O<sub>26</sub>]<sup>4−</sup> cluster in the presence of Mn(CH<sub>3</sub>CO<sub>2</sub>)<sub>3</sub>.
Item Type: | Articles |
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Keywords: | Manganese, mass spectrometry, polyoxometalates, self-assembly |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Cronin, Professor Lee |
Authors: | Wilson, E.F., Miras, H.N., Rosnes, M.H., and Cronin, L. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Journal Abbr.: | Angew Chem Int Ed Engl |
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 24 March 2011 |
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