Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi: 10.1002/chin.201143020)
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Publisher's URL: http://dx.doi.org/10.1002/chin.201143020
Abstract
The influence of the pyramidal heteroanion, TeO<sub>3</sub><sup>2−</sup> in the self-assembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo<sub>12</sub>V<sub>12</sub>Te<sub>3</sub>} (<b>1</b>), {Mo<sub>12</sub>V<sub>12</sub>Te<sub>2</sub>} (<b>2</b>) and {Mo<sub>17</sub>V<sub>8</sub>Te} (<b>3</b>) with the tellurium centres exhibiting the novel µ8-TeO4 and µ9-TeO<sub>3</sub> coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Corella-Ochoa, M.N., Miras, H.N., Kidd, A., Long, D.L., and Cronin, L. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
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