Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}

Corella-Ochoa, M.N., Miras, H.N. , Kidd, A., Long, D.L. and Cronin, L. (2011) Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32-: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}. Chemical Communications, 47(31), pp. 8799-8801. (doi: 10.1002/chin.201143020)

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Publisher's URL: http://dx.doi.org/10.1002/chin.201143020

Abstract

The influence of the pyramidal heteroanion, TeO<sub>3</sub><sup>2−</sup> in the self-assembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo<sub>12</sub>V<sub>12</sub>Te<sub>3</sub>} (<b>1</b>), {Mo<sub>12</sub>V<sub>12</sub>Te<sub>2</sub>} (<b>2</b>) and {Mo<sub>17</sub>V<sub>8</sub>Te} (<b>3</b>) with the tellurium centres exhibiting the novel µ8-TeO4 and µ9-TeO<sub>3</sub> coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Long, Dr Deliang and Cronin, Professor Lee
Authors: Corella-Ochoa, M.N., Miras, H.N., Kidd, A., Long, D.L., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
ISSN:1359-7345
ISSN (Online):1364-548X
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