Bull, D.J., Sorbie, N., Baldissin, G., Moser, D., Telling, M.T.F., Smith, R.I., Gregory, D.H. and Ross, D.K. (2011) In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N. Faraday Discussions, 151, pp. 263-270. (doi: 10.1039/C0FD00020E)
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Publisher's URL: http://dx.doi.org/10.1039/C0FD00020E
Abstract
The hydrogenation of Li<sub>3</sub>N at low chemical potential has been studied <i>in situ</i> by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li<sub>4−2x</sub>NH phase and Li<sub>4</sub>NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li<sub>4</sub>NH and Li<sub>2</sub>NH, which subsequently react together to form Li<sub>4−2x</sub>NH. Possible mechanisms for the production of Li<sub>4</sub>NH from the hydrogenation of Li<sub>3</sub>N are discus
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Sorbie, Miss Natalie and Gregory, Professor Duncan |
Authors: | Bull, D.J., Sorbie, N., Baldissin, G., Moser, D., Telling, M.T.F., Smith, R.I., Gregory, D.H., and Ross, D.K. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry College of Medical Veterinary and Life Sciences > School of Cardiovascular & Metabolic Health |
Journal Name: | Faraday Discussions |
ISSN: | 1359-6640 |
ISSN (Online): | 1364-5498 |
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