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Complexes of the phenylmethane nitronato and propane-2-nitronato anions with divalent metal ions

Cook, J.A., Osborne, M.J., and Rice, D.A. (1976) Complexes of the phenylmethane nitronato and propane-2-nitronato anions with divalent metal ions. Journal of Inorganic and Nuclear Chemistry, 38 (4). pp. 711-713. ISSN 0022-1902 (doi:10.1016/0022-1902(76)80342-9)

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Abstract

Complexes of the nitronato anions PhCHNO2 and (CH3)2CNO2 have been prepared with a variety of divalent metals. Compounds of four stoicheiometries have been isolated; these are MA2, 2L, MA2, B, CuA2, and HgACl (where M = Mn(II), Co(II), Fe(II) or Ni(II), A = nitronato anion, L = monodentate ligand and B = bidentate ligand). The magnetic and spectral properties are interpreted as showing all the species except HgACl to contain 6 coordinate metal atoms. On the evidence of IR spectra, it is possible to distinguish between bridging and chelating nitronato anions by examining the position of νasym NO2 and to deduce that in the species HgACl there are mercury-carbon bonds.

Item Type:Article
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Osborne, Prof Michael
Authors: Cook, J.A., Osborne, M.J., and Rice, D.A.
Subjects:Q Science > QD Chemistry
College/School:College of Social Sciences > School of Education > Social Justice Place and Lifelong Education
Journal Name:Journal of Inorganic and Nuclear Chemistry
ISSN:0022-1902
Published Online:16 May 2003

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