Clark, J.S. , Vignard, D. and Parkin, A. (2011) Synthesis of the tricyclic core of labiatin A and australin A. Organic Letters, 13(15), pp. 3980-3983. (doi: 10.1021/ol201498g)
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Publisher's URL: http://dx.doi.org/10.1021/ol201498g
Abstract
A concise synthesis of the tricyclic core of the marine diterpene natural products labiatin A and australin A has been accomplished. The key ring-forming transformation is a cascade reaction comprising generation of a copper carbenoid from a diazo ketone, intramolecular reaction of the carbenoid with a cyclic ether, and rearrangement of the resulting free oxonium ylide or its metal-bound equivalent with ring expansion of the original cyclic ether.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Clark, Professor Stephen |
| Authors: | Clark, J.S., Vignard, D., and Parkin, A. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Organic Letters |
| ISSN: | 1523-7060 |
| ISSN (Online): | 1523-7052 |
| Published Online: | 06 July 2011 |
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