Bis-tris propane as a new multidentate ligand for nickel- and cobalt-based spin clusters

Ferguson, A., Schmidtmann, M., Brechin, E.K. and Murrie, M. (2011) Bis-tris propane as a new multidentate ligand for nickel- and cobalt-based spin clusters. Dalton Transactions, 40(2), pp. 334-336. (doi: 10.1039/c0dt01090a)

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Publisher's URL: http://dx.doi.org/10.1039/c0dt01090a

Abstract

We describe the first use of Bis-tris propane {2,2′-(propane-1,3-diyldiimino)bis[2-(hydroxymethyl)propane-1,3-diol], H<sub>6</sub>L}, in nickel and cobalt chemistry and report the synthesis, structure and magnetic properties of [Ni<sub>4</sub>(H<sub>4</sub>L)(H<sub>3</sub>L)(acac)<sub>2</sub>]<sup>+</sup> (1) and [Co<sup>II</sup><sub>3</sub>Co<sup>III</sup><sub>2</sub>(H<sub>2</sub>L)<sub>2</sub>(acac)<sub>3</sub>(MeOH)]<sup>+</sup> (2).

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Schmidtmann, Mr Marc and Murrie, Professor Mark
Authors: Ferguson, A., Schmidtmann, M., Brechin, E.K., and Murrie, M.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Dalton Transactions
Journal Abbr.:Dalton Trans.
ISSN:1477-9226
ISSN (Online):1477-9234
Published Online:26 November 2010

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